1313867-41-2

Upstream product

• 1823-14-9 5-phenyl-1-pentyne 
• 1016668-75-9 7-phenyl-2-methylhept-1-en-3-yne 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 

Downstream Products

• 1313867-54-7 4'-methyl-1'-tosyl-1',3,4,5'-tetrahydro-2H-spiro[naphthalene-1,2'-pyrrole] 
• 1373264-06-2 N-(3-(3,4-dihydronaphthalen-1(2H)-ylidene)-2-methylallyl)-4-methylbenzenesulfonamide 

Relevant academic research and scientific papers

Coinage metals-catalyzed cascade reactions of aryl alkynylaziridines: Silver(I)-single vs gold(I)-double cyclizations

Alkynylaziridines carrying an aryl group could be efficiently converted into aminoallenylidene isochromans, isoquinolines, or tetrahydronaphtalenes with silver(I) salts and into 1-azaspiro[4.5]decane derivatives with gold(I) complexes. Mechanistic investi

Gold(i)-catalyzed rearrangement of aryl alkynylaziridines to spiro[isochroman-4,2′-pyrrolines]

Alkynylaziridines carrying an aryl group could be efficiently converted to spiro[isochroman-4,2′-pyrrolines] with gold salts as catalysts. This new rearrangement involved a Friedel-Crafts type intramolecular reaction followed by cyclization of the aminoallene intermediate, both initiated by the dual σ and π Lewis acidities of gold.