1313869-19-0Relevant articles and documents
Palladium-catalyzed coupling of haloalkynes with allyl acetate: A regio- and stereoselective synthesis of (Z)-β-haloenol acetates
Chen, Xiaoyi,Chen, Dongxu,Lu, Zenghui,Kong, Lichun,Zhu, Gangguo
experimental part, p. 6338 - 6343 (2011/10/04)
A Pd-catalyzed coupling of haloalkynes with allyl acetate has been reported, providing a convenient method for the stereoselective synthesis of (Z)-β-haloenol acetates in good yields. The synthetic utility of this method is demonstrated by the formation of functionalized enol acetates via the Suzuki-Miyaura or Sonogashira coupling of the resulting (Z)-β-haloenol acetate products.