1314032-85-3

Basic information

• Product Name: Br^(1-)*C₁₉H₂₉N₄⁽¹⁺⁾
• CAS NO: 1314032-85-3
• Molecular Weight: 393.37
• Mol File: 1314032-85-3.mol

Chemical Properties

• CAS DataBase Reference: Br^(1-)*C₁₉H₂₉N₄⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: Br^(1-)*C₁₉H₂₉N₄⁽¹⁺⁾(1314032-85-3)
• EPA Substance Registry System: Br^(1-)*C₁₉H₂₉N₄⁽¹⁺⁾(1314032-85-3)

Safety Data

• Hazardous Substances Data: 1314032-85-3(Hazardous Substances Data)

Upstream product

• 295-37-4 1,4,8,11-Tetraazacyclotetradecane 
• 100-39-0 benzyl bromide 
• 72738-47-7 decahydro-1H,6H-3a,5a,8a,10a-tetraazapyrene 

Downstream Products

• 1314032-93-3 4-benzyl-11-(tert-butylcarboxy)methyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane 

Relevant articles and documents

Iron(III) Complexes with Cross-Bridged Cyclams: Synthesis and Use in Alcohol and Water Oxidation Catalysis

A class of iron(III) complexes containing diversely substituted cross-bridged cyclams (1-R,R′: 1-Me,Me, 1-Me,Et, 1-Et,Et, 1-Me,Bn, 1-Bn,Bn) has been prepared and characterized. (1-R,R′) complexes catalyze the oxidation of alcohols to ketones in green cond

Reinforced cyclam derivatives functionalized on the bridging unit

A new synthetic method has been developed for the preparation of reinforced cyclams (1,4,8,11-tetraazacyclotetradecane) C-functionalized on the bridging unit, by using a "one pot" reaction starting from the appropriate bis-aminal cyclam intermediate. The high reactivity of quaternized aminal moiety toward nucleophilic agent has been used to elaborate a new class of cross-bridged and side-bridged cyclam derivatives containing cyanide group on the ethylene bridge. Several chelators and corresponding copper(ii) complexes have been prepared and characterized by X-ray diffraction. These new constrained polyazamacrocycles are valuable precursors of bifunctional chelating agents for the preparation of PET radiotracers.