131429-79-3Relevant academic research and scientific papers
Pd-catalyzed ScN′ reactions: Stereoselective formation of cyclic carbamates from tert-butyldimethylsilyl carbamates
Spears, Glen W.,Nakanishi, Koji,Ohfune, Yasufumi
, p. 5339 - 5342 (1990)
Stereo selective formation of cyclic carbamates was achieved by the intramolecular trapping of a tert-butyldimethylsilyloxycarbonyl group with allylic esters upon activation with fluoride and cat. Pd(O). The reactive conformation is proposed to be D. The
