1314380-01-2

Upstream product

• 120520-79-8 2-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)ethyl aldehyde 
• 136029-15-7 1-(thiazol-2-yl)-2-(triphenyl-λ ⁵-phosphanylidene)ethan-1-one 
• 83-87-4 D-Mannose pentaacetate 

Downstream Products

• 1314380-12-5 (2R,4R)-2-[(S)-2-(benzyloxy)-1-phenylethoxy]-4-[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl]-6-formyl-3,4-dihydro-2H-pyran 
• 1314380-13-6 (2S,4S)-2-[(R)-2-(benzyloxy)-1-phenylethoxy]-4-[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl]-6-formyl-3,4-dihydro-2H-pyran 
• 1314380-08-9 C₅₁H₅₃NO₈S 
• 1314380-16-9 (S)-2-benzyloxy-1-phenylethyl 2,3-dideoxy-3-C-[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl]-4,6-di-O-benzyl-β-D-arabino-hexopyranoside 
• 1314380-17-0 (R)-2-(benzyloxy)-1-penylethyl 2,3-dideoxy-3-C-[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl]-4,6-di-O-benzyl-β-L-arabino-hexopyranoside 
• 1314380-21-6 phenyl-1-thio 2,3-dideoxy-3-C-[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl]-4,6-di-O-benzyl-β-D-arabino-hexopyranoside 
• 1314380-20-5 phenyl-1-thio 2,3-dideoxy-3-C-[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl]-4,6-di-O-benzyl-α-D-arabino-hexopyranoside 
• 1314380-22-7 phenyl-1-thio 2,3-dideoxy-3-C-[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl]-4,6-di-O-benzyl-β-L-arabino-hexopyranoside 
• 1314380-23-8 phenyl-1-thio 2,3-dideoxy-3-C-[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl]-4,6-di-O-benzyl-α-L-arabino-hexopyranoside 
• 1314380-07-8 (2R,4R)-2-[(S)-2-(benzyloxy)-1-phenylethoxy]-4-[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl]-6-(thiazol-2-yl)-3,4-dihydro-2H-pyran 
• 1314380-09-0 (2S,4S)-2-[(R)-2-(benzyloxy)-1-phenylethoxy]-4-[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl]-6-(thiazol-2-yl)-3,4-dihydro-2H-pyran 
• 1314380-04-5 methyl (R)-2-phenyl-2-{[(2S,4S)-4-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl-6-(thiazol-2-yl)-3,4-dihydro-2H-pyran-2-yl]oxy}acetate 
• 1314380-03-4 methyl (S)-2-phenyl-2-{[(2R,4R)-4-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)methyl-6-(thiazol-2-yl)-3,4-dihydro-2H-pyran-2-yl]oxy}acetate 

Relevant academic research and scientific papers

Stereoselective preparation of four 3-C-mannosylated D- and L-glucals from a single starting compound

The corresponding oxadiene, prepared from the starting perbenzylated α-d-mannopyranosylethanal was subjected to stereoselective cycloaddition reactions with R and S methyl (ethenyloxy)(phenyl)acetates. From the two obtained diastereoisomeric cycloadducts,