1314380-06-7

Upstream product

• 136029-15-7 1-(thiazol-2-yl)-2-(triphenyl-λ ⁵-phosphanylidene)ethan-1-one 
• 1314380-02-3 (E)-4-(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl)-1-(thiazol-2-yl)-but-2-en-1-one 
• 149070-69-9 methyl (R)-(ethenyloxy)(phenyl)acetate 

Downstream Products

• 1314380-11-4 (2S,4S)-2-[(R)-2-(benzyloxy)-1-phenylethoxy]-4-[(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl)methyl]-6-(thiazol-2-yl)-3,4-dihydro-2H-pyran 
• 1314380-15-8 (2S,4S)-2-[(R)-2-(benzyloxy)-1-phenylethoxy]-4-[(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl)methyl]-6-formyl-3,4-dihydro-2H-pyran 
• 1314380-19-2 (S)-2-(benzyloxy)-1-phenylethyl 2,3-dideoxy-3-C-[(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl)methyl]-4,6-di-O-benzyl-β-L-arabino-hexopyranoside 
• 1314380-26-1 phenyl-1-thio 2,3-dideoxy-3-C-[(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl)methyl]-4,6-di-O-benzyl-β-L-arabino-hexopyranoside 
• 1314380-27-2 phenyl-1-thio 2,3-dideoxy-3-C-[(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl)methyl]-4,6-di-O-benzyl-α-L-arabino-hexopyranoside 

Relevant academic research and scientific papers

Stereoselective preparation of four 3-C-mannosylated D- and L-glucals from a single starting compound

The corresponding oxadiene, prepared from the starting perbenzylated α-d-mannopyranosylethanal was subjected to stereoselective cycloaddition reactions with R and S methyl (ethenyloxy)(phenyl)acetates. From the two obtained diastereoisomeric cycloadducts,