13145-54-5

Basic information

• Product Name: 4-Benzhydryl-2,6-di-tert-butylphenol
• Synonyms: 4-Benzhydryl-2,6-di-tert-butylphenol
• CAS NO: 13145-54-5
• Molecular Formula: C₂₇H₃₂O
• Molecular Weight: 0
• Mol File: 13145-54-5.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 433.3°Cat760mmHg
• Flash Point: 198.1°C
• Appearance: /
• Density: 1.022g/cm³
• Vapor Pressure: 4.09E-08mmHg at 25°C
• Refractive Index: 1.564
• CAS DataBase Reference: 4-Benzhydryl-2,6-di-tert-butylphenol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Benzhydryl-2,6-di-tert-butylphenol(13145-54-5)
• EPA Substance Registry System: 4-Benzhydryl-2,6-di-tert-butylphenol(13145-54-5)

Safety Data

• Hazardous Substances Data: 13145-54-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C27H32O/c1-26(2,3)22-17-21(18-23(25(22)28)27(4,5)6)24(19-13-9-7-10-14-19)20-15-11-8-12-16-20/h7-18,24,28H,1-6H3

Upstream product

• 13131-76-5 2,6-di-tert-butyl-4-(diphenylmethylene)-2,5-cyclohexadien-1-one 
• 74-88-4 methyl iodide 
• 98-86-2 acetophenone 
• 91-01-0 1,1-Diphenylmethanol 
• 128-39-2 2,6-di-tert-butylphenol 

Downstream Products

• 13131-76-5 2,6-di-tert-butyl-4-(diphenylmethylene)-2,5-cyclohexadien-1-one 

Relevant articles and documents

Uranyl-catalyzed hydrosilylation ofpara-quinone methides: access to diarylmethane derivatives

An efficient and convenient uranyl-catalyzed reductive hydrosilylation reaction ofpara-quinone methides (p-QMs) was developed by employing silane as the reductant. The hydrosilylation procedure using the UO2(NO3)2·6H2

Synthesis and cytotoxic evaluation of thiourea and N-bis-benzothiazole derivatives: A novel class of cytotoxic agents

Benzothiazolyl thiocarbamides has been achieved using a catalytic amount of 4-dimethylaminopyridine (DMAP) followed by its chemoselective oxidative cyclization with 1,3-di-n-butylimidazolium tribromide[bbim][Br3] to afford the N-bis-benzothiazole derivatives. All the synthesized compounds were evaluated for cytotoxic activity against two human monocytic cell lines (U 937, THP-1) and a mouse melanoma cell line (B16-F10). Based on their IC50 values, the majority of the benzothiazolyl thiocarbamides and N-bis-benzothiazoles had significant antiproliferative activity on U 937 and B16-F10 cells, the compounds 3b, 3e, 3f, 3k, 6c and 6h were found to be the most active. The present findings indicate clearly that the compound 3e exhibited more antiproliferative activity on U 937 cells than the standard molecule, etoposide. Nevertheless, these compounds have shown comparatively less cytotoxicity towards THP-1 cells.

Electroorganic Reactions. 31. Quinonemethide Radical-Anions and Dianoins: Their Cathodic Generation and Reactivity

The cathodic reactions of a number of relatively stable quinonemethides have been examined in detail by cyclic voltammetry, controlled potential coulometry, and rigorous product analysis following preparative-scale electrolyses.The results of cyclic voltammetric experiments differ in some respects from those of earlier polarographic work.The lifetimes of the electrogenerated radical-anions and dianions, in the absence of added electrophile, are governed by steric hindrance.Hindered intermediates are relatively long-lived yet hydrogenate in the presence of proton donor and alkylate in the presence of methyl iodide.Less hindered analogue efficiently and rapidly dimerize, at carbon, with concomitant protonation or O-methylation depending on added electrophile.The ambident cathodically generated nucleophiles alkylate at both carbon and oxygen, and the competition is crucially dependent on the cation (Bu4N+ or Li+).Fuchsone 3 gives reduction products which vary with initial concentration and on the presence, or otherwise, of oxygen.Efficient reaction between oxygen and triarylmethyl radicals generated, e.g., from 3 has been demonstrated.