1314555-75-3Relevant academic research and scientific papers
Cationic palladium-catalyzed [5 + 2] annulation of 2-acylmethoxyarylboronic acids and allenoates: Synthesis of 1-benzoxepine derivatives
Yu, Xufen,Lu, Xiyan
, p. 6350 - 6355 (2011/10/02)
The 1-benzoxepine derivatives were synthesized conveniently by cationic palladium-catalyzed [5 + 2] annulation reaction of 2-acylmethoxyarylboronic acids with allenoates in high yields. This annulation involves the intramolecular nucleophilic addition to ketones without the formation of π-allylpalladium species.
