1314664-72-6

Basic information

• Product Name: C₁₅H₂₃NOSi
• Synonyms: C₁₅H₂₃NOSi
• CAS NO: 1314664-72-6
• Molecular Weight: 261.439
• Mol File: 1314664-72-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₂₃NOSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₂₃NOSi(1314664-72-6)
• EPA Substance Registry System: C₁₅H₂₃NOSi(1314664-72-6)

Safety Data

• Hazardous Substances Data: 1314664-72-6(Hazardous Substances Data)

Upstream product

• 1199-59-3 4-dimethylamino-o-tolualdehyde 
• 1066-54-2 trimethylsilylacetylene 
• 63082-45-1 4-fluoro-2-methylbenzaldehyde 

Relevant articles and documents

SN1-type reactions in the presence of water: Indium(III)-promoted highly enantioselective organocatalytic propargylation of aldehydes

Water under troubled chemistry! The first catalytic stereoselective addition of aldehydes to internal functionalized propargylic alcohols promoted by a combination of organocatalysis and indium triflate is described (see scheme). The reaction is tolerant of functional groups (FG) and was performed in the presence of water. High enantioselectivities (anti, 92-99 % ee) and moderate diastereomeric ratios (d.r., up to 6.7:1 for the anti isomer) were obtained. Copyright