131467-47-5Relevant academic research and scientific papers
Synthese regioselective d'amines α-alleniques par aminomethylation-desilylation de propargyltrimethylsilanes
Damour, D.,Pornet, J.,Randrianoelina, B.,Miginiac, L.
, p. 289 - 297 (1990)
A very convenient method to prepare α-allenic amines from propargyltrimethylsilanes and secondary amines via an aminomethylation-desilylation process is described
Methods for the preparation of allenes employing indium- and zinc-mediated dehalogenation reactions in aqueous solutions
Lin, Mei-Huey,Tsai, Wen-Shing,Lin, Long-Zhi,Hung, Shiang-Fu,Chuang, Tsung-Hsun,Su, Yi-Jen
, p. 8518 - 8523 (2012/01/19)
Simple and mild methods for the synthesis of allenes, employing indium- and zinc-mediated dehalogenation reactions of vicinal dihalides in an aqueous solvent, are described. By using these procedures, various allenylmethyl aryl ethers and monosubstituted
Regio- and stereoselective synthesis of 1,4-dienes
Oishi, Shigeki,Hatano, Keisuke,Tsubouchi, Akira,Takeda, Takeshi
body text, p. 11639 - 11640 (2011/12/02)
Titanocene(ii)-promoted cross-coupling between (Z)-alkenyl methyl sulfones and terminal allenes produced 1,4-dienes regioselectively via the formation of 2-alkylidenetitanacyclopentanes. Preferential formation of E,Z-dienes was observed in the reaction us
Water-Tolerant Unstabilized Carbanion Equivalents: Bismuth(III) Chloride-Aluminum Promoted Alkylations of Immonium Cations to Amines in Aqueous Media
Katritzky, Alan. R.,Shobana, Navayath,Harris, Philip A.
, p. 4247 - 4248 (2007/10/02)
In the presence of bismuth(III) chloride-metallic aluminum, alkyl as well as allyl halides react with N-(alkylamino)benzotriazoles at 20 deg C in THF-water to give the corresponding homoalkylated amines in high yields.
