131469-64-2Relevant academic research and scientific papers
IBX/LiBr-promoted one-pot oxidative anti-Markownikov bromohydroxylation/bromoalkoxylation of Baylis-Hillman olefins
Yadav, Lal Dhar S.,Awasthi, Chhama
experimental part, p. 715 - 718 (2011/02/27)
The first example of one-pot oxidative anti-Markownikov bromohydroxylation and bromoalkoxylation of Baylis-Hillman (BH) adducts (olefins) is reported. The reaction is performed at rt using LiBr as the bromine source and 2-iodoxybenzoic acid (IBX) as the o
Organic reactions in water: An efficient one-pot synthesis of acyloxiranes from Baylis-Hillman adducts using hypervalent iodine
Das, Biswanath,Holla, Harish,Venkateswarlu, Katta,Majhi, Anjoy
, p. 8895 - 8897 (2007/10/03)
Treatment of Baylis-Hillman adducts with iodosobenzene (PhIO) in the presence of a catalytic amount of KBr in water at room temperature afforded the corresponding acyloxiranes in good yields.
One-Pot Preparation of 1-Acyl-1-methoxycarbonyloxiranes and 1-Acyl-1-cyanooxiranes from Methyl 3-Hydroxy-2-methylenealkanoates or 3-Aryl-3-hydroxy-2-methylenepropanenitriles
Foucaud, Andre,Rouille, Eliane de
, p. 787 - 789 (2007/10/02)
The reaction of sodium hypochlorite with methyl 3-hydroxy-2-methylenealkanoates or 3-aryl-3-hydroxy-2-methylenepropanenitriles, dispersed on silica gel, in acetonitrile leads to oxidation of the alcohol function and epoxidation of the methylene group to g
