1314801-34-7Relevant academic research and scientific papers
Triisopropylsilylethynyl substituted benzodithiophene copolymers: Synthesis, properties and photovoltaic characterization
Zhu, Enwei,Luo, Guoping,Liu, Yun,Yu, Jiangsheng,Zhang, Fujun,Che, Guangbo,Wu, Hongbin,Tang, Weihua
, p. 1595 - 1603 (2015)
We demonstrated herein the facile synthesis of triisopropylsilylethynyl (TIPS) functionalized benzo[1,2-b:4,5-b′]dithiophene (BDT). Three new TIPSBDT-based donor-acceptor alternating copolymers were further developed by Pd-catalyzed Stille coupling. The effect of accepting unit structure on the optical, electrochemical and energy levels of the polymer was studied. The positive impact of PFN layer, high-boiling solvents processing, polar solvent treatment and solvent annealing on the performance of polymer:PC71BM bulk heterojunction solar cells was revealed. The best devices delivered a power conversion efficiency of 5.46% when blend films processed using o-dichlorobenzene with 3 vol% DIO and treated with the optimization of THF annealing and insertion of PFN layer. The device performance was correlated with the morphology evolution of blend films processed with solvent choice, methanol treatment and THF annealing.
Highly efficient polymer solar cells based on poly(carbazole-alt-thiophene- benzofurazan)
Zhang, Bin,Hu, Xiaowen,Wang, Minquan,Xiao, Huiping,Gong, Xiong,Yang, Wei,Cao, Yong
, p. 2042 - 2047 (2012)
An octyloxy substituted benzofurazan based poly(carbazole-alt-thiophene- benzofurazan) (PCzDTBF) was synthesized by Suzuki polycondensation. The absorption spectra of the polymer were peaked at 385 and 540 nm, and the HOMO and LUMO energy levels were -5.3
Crystalline low-band gap polymers comprising thiophene and 2,1,3-benzooxadiazole units for bulk heterojunction solar cells
Jiang, Jian-Ming,Yang, Po-An,Hsieh, Tsung-Hsuan,Wei, Kung-Hwa
, p. 9155 - 9163 (2011)
We have used Stille coupling polymerization to synthesize a series of new crystalline low-band gap conjugated polymers-PTHBO, PBTTBO, and PTTTBO-constituting mainly electron-rich thiophene (TH), 2,2′-bithiophene (BT), and thieno[3,2-b]thiophene (TT) units
Investigation of Optical and Electrochemical Properties of Benzene Based Solution Processable 2,1,3-Benzooxadiazole Comprising Polymers
Goker, Seza,Hacioglu, Serife O.,Hizalan, Gonul,Toppare, Levent
, (2020/10/09)
Four novel solution processable benzooxadiazole containing alternating copolymers namely poly (5,6-bis(octyloxy)-4-(5-phenylthiophen-2-yl)-7-(thiophen-2-yl)benzo[c][1,2,5]oxadiazole)PBOTPh, poly (5,6-bis(octyloxy)-4-(5-phenylselenophen-2-yl)-7-(selenophen
Synthesis, characterization, and photovoltaic properties of a low-bandgap copolymer based on 2,1,3-benzooxadiazole
Jiang, Jian-Ming,Yang, Po-An,Chen, Hsiu-Cheng,Wei, Kung-Hwa
supporting information; experimental part, p. 8877 - 8879 (2011/09/21)
PBDTBO, a conjugated polymer comprising benzo[1,2-b:4,5-b′] dithiophene (BDT) and 5,6-bis(octyloxy)benzo[c][1,2,5]oxadiazole (BO) units, exhibits a deep HOMO energy level of -5.27 eV and excellent solubility. A device incorporating PBDTBO and [6,6]-phenyl-C61-butyric acid methyl ester (1:1, w/w) exhibited a power conversion efficiency of 5.7%.
