1314865-17-2

Upstream product

• 1314865-13-8 2-[(N-benzyloxycarbonyl)amino]ethyl 3-O-(3-methoxy)-benzyl-α-L-rhamnopyranoside 
• 1314865-14-9 2-[(N,N'-benzyl-benzyloxycarbonyl)amino]ethyl 2,4-di-O-benzyl-3-O-(3-methoxy)benzyl-α-L-rhamnopyranoside 
• 1314865-15-0 2-[(N,N'-benzyl-benzyloxycarbonyl)amino]ethyl 2,4-di-O-benzyl-α-L-rhamnopyranoside 
• 1314865-16-1 2-[(N,N-benzyl-benzyloxycarbonyl)amino]ethyl O-(2-O-acetyl-4-azido-3-O-benzyl-4,6-dideoxy-α-D-glucopyranosyl)-(1→3)-2,4-di-O-benzyl-α-L-rhamnopyranoside 

Downstream Products

• 1314865-20-7 C₅₁H₆₀N₂O₁₀ 
• 1314865-19-4 2-[(N,N'-benzyl-benzyloxycarbonyl)amino]ethyl O-[3-O-benzyl-4-(3-hydroxy-3-methylbutanamido)-4,6-dideoxy-2-O-methyl-R-D-glucopyranosyl]-(1→3)-2,4-di-O-benzyl-α-L-rhamnopyranoside 
• 1314865-18-3 2-[(N,N'-benzyl-benzyloxycarbonyl)amino]ethyl O-(4-azido-3-O-benzyl-4,6-dideoxy-2-O-methyl-R-D-glucopyranosyl)-(1→3)-2,4-di-O-benzyl-R-L-rhamnopyranoside 

Relevant academic research and scientific papers

Access to antigens related to anthrose using pivotal cyclic sulfite/sulfate intermediates

Anthrose is the upstream terminal unit of the tetrasaccharide side chain from a major glycoprotein of Bacillus anthracis exosporium and is part of important antigenic determinants. A novel entry to anthrose-containing antigens and precursors is described. The synthetic route, starting from d(+)-fucose, makes use of intermediates featuring a cyclic sulfite or sulfate function which serves successively as a protecting and a leaving group.