1314889-48-9Relevant academic research and scientific papers
Asymmetric synthesis of (+)-geranyllinaloisocyanide: Assignment of absolute stereochemistry
Ichikawa, Yoshiyasu,Matsuda, Yasunori,Okumura, Ken,Nakamura, Mitsuhiro,Masuda, Toshiya,Kotsuki, Hiyoshizo,Nakano, Keiji
, p. 2520 - 2523 (2011/06/22)
The first nonracemic synthesis of (+)-geranyllinaloisocyanide, starting with (-)-lactic acid methyl ester, has been accomplished by exploiting a [3.3] sigmatropic rearrangement of allyl cyanate. The synthesis enables assignment of the S configuration of the C(3) isocyano substituted, quaternary stereogenic center in natural geranyllinaloisocyanide.
