851626-19-2

Upstream product

• 1314889-48-9 C₂₆H₃₈O₃Si 
• 1314889-47-8 C₁₀H₂₀O₃ 
• 851682-47-8 (Z)-(S)-2-Methyl-4-(tetrahydro-pyran-2-yloxy)-pent-2-enoic acid ethyl ester 
• 114191-19-4 (4S,2E)-ethyl 4-hydroxy-2-methylpent-2-enoate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 851626-26-1 (S,E)-2-methylpent-2-ene-1,4-diol 

Downstream Products

• 1247930-65-9 C₂₃H₃₁NO₃Si 
• 1314895-87-8 C₂₃H₂₉NO₂Si 
• 1295580-98-1 (S,E)-tert-butyl 1-(tert-butyldiphenylsilyloxy)-2-methylpent-3-en-2-ylcarbamate 
• 851626-45-4 (2RS,1'S,2'E) 2-(4-methoxybenzyloxy)hex-5-enoic acid 4'-(tert-butyl(diphenyl)silyloxy)-1',3'-dimethylbut-2'-enyl ester 
• 869102-86-3 (2S,4R)-2-(4-Methoxy-benzyloxy)-4-methyl-hex-5-ynoic acid (E)-(S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-but-2-enyl ester 

Relevant academic research and scientific papers

Asymmetric synthesis of (+)-geranyllinaloisocyanide: Assignment of absolute stereochemistry

The first nonracemic synthesis of (+)-geranyllinaloisocyanide, starting with (-)-lactic acid methyl ester, has been accomplished by exploiting a [3.3] sigmatropic rearrangement of allyl cyanate. The synthesis enables assignment of the S configuration of the C(3) isocyano substituted, quaternary stereogenic center in natural geranyllinaloisocyanide.

Asymmetric hydrogenation approaches to valuable, acyclic 1,3-hydroxymethyl chirons

An iridium carbene oxazoline complex was used to catalyze hydrogenations of trisubstituted alkenes to give terminal and internal 1,3-hydroxymethyl chirons. The products are accessible in all possible stereoisomeric forms. These hydrogenations do not requi

Highly enantioselective sequential Claisen-Ireland/metathesis: Synthesis of cycloalkenes bearing two contiguous highly functionalized asymmetric centres

A sequence of two reactions, consisting of a highly stereoselective silylated ketene acetal Claisen-Ireland rearrangement followed by a ring closing metathesis, gave a stereocontrolled access to various carbocycles.