1314963-18-2Relevant articles and documents
[1,5]-H shift of aldehyde hydrogen in dienal compounds to produce ketenes
Sakaguchi, Taku,Okuno, Yudai,Tsutsumi, Yohei,Tsuchikawa, Hiroshi,Katsumura, Shigeo
, p. 4292 - 4295 (2011)
In 3-ethoxycarbonyl-2,4-dienal compounds, a thermal [1,5]-H shift of aldehyde hydrogen easily proceeded to produce the corresponding vinyl ketenes due to the remarkable substituent effect caused by the C3 ester group. The produced ketenes were captured by