13151-04-7

Basic information

• Product Name: 5-METHYL-1-HEPTENE
• Synonyms: 5-Methylhept-1-ene;5-METHYL-1-HEPTENE
• CAS NO: 13151-04-7
• Molecular Formula: C₈H₁₆
• Molecular Weight: 112.21
• Mol File: 13151-04-7.mol
• Article Data: 5

Chemical Properties

• Melting Point: -103.01°C (estimate)
• Boiling Point: 113.3°C
• Flash Point: 15.5 °C
• Appearance: /
• Density: 0.7122
• Vapor Pressure: 25.7mmHg at 25°C
• Refractive Index: 1.4069
• CAS DataBase Reference: 5-METHYL-1-HEPTENE(CAS DataBase Reference)
• NIST Chemistry Reference: 5-METHYL-1-HEPTENE(13151-04-7)
• EPA Substance Registry System: 5-METHYL-1-HEPTENE(13151-04-7)

Safety Data

• Hazardous Substances Data: 13151-04-7(Hazardous Substances Data)

Usage

Description

5-Methyl-1-heptene, also known as 1-heptene-5-methyl or 5-methylhept-1-ene, is a branched-chain alkene with the molecular formula C8H16. It is classified as an alpha-olefin and is characterized by its colorless liquid form, mild odor, and flammable nature. This chemical is relatively stable under normal conditions but requires careful handling and storage away from ignition sources and incompatible materials. 5-Methyl-1-heptene is a versatile chemical with a range of industrial applications, including the production of synthetic rubber and plastics, as well as serving as a solvent and a chemical intermediate in the synthesis of various organic compounds.

Uses

Used in Chemical Synthesis Industry:
5-Methyl-1-heptene is used as a chemical intermediate for the synthesis of various organic compounds, contributing to the development of new materials and products.
Used in Plastics and Rubber Industry:
5-Methyl-1-heptene is used as a key component in the production of synthetic rubber and plastics, enhancing the versatility and performance of these materials.
Used as a Solvent:
5-Methyl-1-heptene is utilized as a solvent in various industrial processes, facilitating chemical reactions and material processing.
Used in Research and Development:
5-Methyl-1-heptene serves as a valuable compound in research and development, enabling scientists to explore its properties and potential applications in different fields.

InChI:InChI=1/C8H16/c1-4-6-7-8(3)5-2/h4,8H,1,5-7H2,2-3H3

Upstream product

• 592-42-7 1,5-Hexadien 
• 97-93-8 triethylaluminum 
• 137-32-6 (-)-2-Methylbutan-1-ol 
• 534-00-9 (+)-1-bromo-2-methylbutane 
• 106-95-6 allyl bromide 
• 10422-35-2 1-bromo-2-methyl-butane 
• 557-18-6 diethylmagnesium 

Downstream Products

• 60609-52-1 (E)-14-Methyl-8-Hexadecenal 
• 60609-53-2 (Z)-14-Methyl-8-Hexadecenal 
• 71566-65-9 7-methyl-1-nonyne 
• 7212-53-5 5-methyl-1-heptanol 

Relevant articles and documents

Synthesis and transformations of metallacycles 46. Catalytic cycloalumination reaction in the synthesis of bis(phospholanes)

An efficient one-pot synthesis of bis(phospholanes) was elaborated, which included a sequential Cp2ZrCl2-catalyzed cycloalumination of α,ω-diolefins with AlEt3, giving the corresponding bis(aluminacyclopentanes), and their in situ reaction with dihalophosphines to furnish the target α,ω-bis(phospholanes). The reaction of these compounds with H2O2 or elementary sulfur gave the corresponding bis(phospholane 1-oxides) and bis(phospholane 1-sulfides).

Cyclization of methyl-substituted 6-heptenyl radicals

(Matrix presented) The behavior of a series of methyl-substituted 6-heptenyl radicals, generated from the corresponding iodides ((Me3Si)3SiH, AIBN in benzene at 80°C), has been investigated. The stereoselectivity of the 6-exo cyclizations, affording dimethylcyclohexanes, is low, and sizable quantities of methylcycloheptane, generated via 7-endo cyclization, are also produced.

SYNTHETIC INVESTIGATIONS INTO INSECT-ATTRACTING SUBSTANCES (SEX ATTRACTANTS). IV. SYNTHESIS OF 14-METHYL-8-cis-HEXADECENAL AND 14-METHYL-8-trans-HEXADECENAL, COMPONENTS OF THE SEX PHEROMONE OF THE DERMESTID BEETLE Trogoderma granarium EVERTS

14-Methyl-8-hexadecyn-1-ol was obtained by the alkylation of 7-methyl-1-nonyne with heptamethylene chlorohydrin.Its hydrogenation in the presence of colloidal nickel catalyst was used for the synthesis of 14-methyl-8-cis-hexadecen-1-ol, and reduction with lithium aluminum hydride was used for the synthesis of 14-methyl-8-trans-hexadecen-1-ol.Both ethylenic alcohols were converted by oxidation into the corresponding aldehydes, which are the main components of the sex pheromone of the dermestid beetle.