13151-28-5Relevant academic research and scientific papers
An efficient method for conversion of 1-alken-3-yl carbonates to 1- alkenes and 3-chloro-1-alkenes via allyltitaniums
Matsuda, Shin-Ichiro,An, Duk Keun,Okamoto, Sentaro,Sato, Fumie
, p. 7513 - 7516 (1998)
Hydrolysis and halogenolysis of the allyltitaniums derived from allylic carbonates and a Ti(O-i-Pr)4/2 i-PrMgCl reagent proceed with high regio- and stereoselectivity, thus providing an efficient method for converting 1- alken-3-yl carbonates to 1-alkenes or 3-chloro-1-alkenes.
