Tetrahedron Letters p. 7513 - 7516 (1998)
Update date:2022-09-26
Topics:
Matsuda, Shin-Ichiro
An, Duk Keun
Okamoto, Sentaro
Sato, Fumie
Hydrolysis and halogenolysis of the allyltitaniums derived from allylic carbonates and a Ti(O-i-Pr)4/2 i-PrMgCl reagent proceed with high regio- and stereoselectivity, thus providing an efficient method for converting 1- alken-3-yl carbonates to 1-alkenes or 3-chloro-1-alkenes.
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