131516-07-9Relevant academic research and scientific papers
Enantioselective Intermolecular Heck and Reductive Heck Reactions of Aryl Triflates, Mesylates, and Tosylates Catalyzed by Nickel
Huang, Xiaolei,Teng, Shenghan,Chi, Yonggui Robin,Xu, Wenqiang,Pu, Maoping,Wu, Yun-Dong,Zhou, Jianrong Steve
supporting information, p. 2828 - 2832 (2020/12/11)
Nickel-catalyzed intermolecular Heck reaction of cycloalkenes proceeds well with aryl triflates, mesylates and tosylates in excellent enantiomeric ratios. The asymmetric reductive Heck reaction also works with a 2-cyclopentenone ketal, which is equivalent to conjugate arylation of the enone itself.
Regio- and enantio-selective Heck reactions of aryl and alkenyl triflates with the new chiral ligand (R)-BITIANP
Tietze, Lutz F.,Thede, Kai,Sannicolo, Franco
, p. 1811 - 1812 (2007/10/03)
The Heck reaction of dihydrofuran 3 with aryl triflates 4 and 6a-d and alkenyl triflate 8 in the presence of the chiral ligand (R)-BITIANP 1 provides the 2-substituted 2,3-dihydrofurans 5a, 7a-d and 9, respectively, with complete regioselectivity, high en
Palladium-catalyzed asymmetric arylation of 2,3-dihydrofuran: 1,8-Bis(dimethylamino)naphthalene as an efficient base
Ozawa, Fumiyuki,Kubo, Akihiko,Hayashi, Tamio
, p. 1485 - 1488 (2007/10/02)
Reaction of 2,3-dihydrofuran with aryl triflate (1) in the presence of a base and a palladium catalyst, generated in situ from Pd(OAc)2 and (R)-BINAP, gave (R)-2-aryl-2,3-dihydrofuran (2) and a small amount of (S)-2-aryl-2,5-dihydrofuran (3). T
