131529-65-2

Upstream product

• 66537-92-6 methyl 2,3-anhydro-4,6-benzylidene-α-D-allopyranoside 
• 131529-42-5 methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-C-(2-methoxycarbonylethyl)-α-D-altroside 
• 131529-55-0 methyl 3-O-benzyl-6-O-t-butyldimethylsilyl-2-deoxy-2-C-(2-methoxycarbonylethyl)-α-D-arabino-hexosid-4-ulose 
• 131529-54-9 methyl 3-O-benzyl-6-O-t-butyldimethylsilyl-2-deoxy-2-C-(2-methoxycarbonylethyl)-α-D-altropyranoside 
• 131529-47-0 methyl 3-O-benzyl-2-deoxy-2-C-(2-methoxycarbonylethyl)-α-D-altropyranoside 
• 100-39-0 benzyl bromide 
• 126108-10-9 methyl 4,6-O-benzylidene-2-deoxy-2-(2-propenyl)-α-D-allohexopyranoside 
• 128142-89-2 methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-C-(3-hydroxypropyl)-α-D-altroside 
• 131529-56-1 methyl 3-O-benzyl-6-O-t-butyldimethylsilyl-2,4-dideoxy-2-C-(2-methoxycarbonylethyl)-4-C-methylene-α-D-arabino-hexoside 

Relevant academic research and scientific papers

The Synthesis of Some Carbohydrate-Derived Precursors to Tylonolide, the Aglycon of the Antibiotic Tylosin

Treatment of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-alloside with the anion derived from trimethyl(prop-1-ynyl)silane, allylmagnesium chloride or isobutenylmagnesium chloride introduces a three- or four-carbon substituent at C2 of the sugar.In each case