1315305-55-5Relevant articles and documents
Planar macrocyclic fluoropentamers as supramolecular organogelators
Ren, Changliang,Xu, Shengyu,Xu, Jun,Chen, Hongyu,Zeng, Huaqiang
, p. 3840 - 3843 (2011/09/19)
Despite their great diversities, 2D-shaped macrocycles that can serve as the organogelators have been surprisingly rare; two planar macrocyclic fluoropentamers designed by us were highly able to gelate organic solvents, largely derived from their strong tendency to form 1D stacked fibrillar structures stabilized by both interplanar H-bonds and π-π stacking forces.
Crystallographic realization of the mathematically predicted densest all-pentagon packing lattice by C5-symmetric "sticky" fluoropentamers
Ren, Changliang,Zhou, Feng,Qin, Bo,Ye, Ruijuan,Shen, Sheng,Su, Haibin,Zeng, Huaqiang
, p. 10612 - 10615 (2012/01/04)
Regular pentagonal adhesive tiles were obtained by designing a cyclic fluoropentamer with an internal CF...HN H-bonded network and "sticky" edges that can glue the molecules together through intermolecular CArH...O=C H bonds. In the crystal they form the mathematically predicted densest all-pentagon 2D lattice with a packing density of 0.921 (see picture). Copyright