1315482-76-8Relevant academic research and scientific papers
Lithium cation enhances anion binding in a tripodal phosphine oxide-based ditopic receptor
Gavette, Jesse V.,Lara, Juven,Berryman, Orion B.,Zakharov, Lev N.,Haley, Michael M.,Johnson, Darren W.
, p. 7653 - 7655 (2011)
A tripodal ditopic receptor presents H-bond donors and a phosphine oxide to potential guests. In the idealized binding conformation, an endohedral PO functionality provides enhanced halide binding in the presence of lithium with the greatest ΔΔG° observed for bromide, while minimal changes in Ka are observed in the presence of sodium.
