1315577-30-0

Basic information

• Product Name: C₁₄H₂₃FO₂Si
• Synonyms: C₁₄H₂₃FO₂Si
• CAS NO: 1315577-30-0
• Molecular Weight: 270.419
• Mol File: 1315577-30-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₄H₂₃FO₂Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₂₃FO₂Si(1315577-30-0)
• EPA Substance Registry System: C₁₄H₂₃FO₂Si(1315577-30-0)

Safety Data

• Hazardous Substances Data: 1315577-30-0(Hazardous Substances Data)

Upstream product

• 371-41-5 4-Fluorophenol 
• 56310-18-0 di-tert-butylchlorosilane 

Downstream Products

• 1344113-54-7 4-fluorocatechol diacetate 
• 367-32-8 4-fluoropyrocatechol 

Relevant articles and documents

Synthesis of catechols from phenols via Pd-catalyzed silanol-directed C-H oxygenation

A silanol-directed, Pd-catalyzed C-H oxygenation of phenols into catechols is presented. This method is highly site selective and general, as it allows for oxygenation of not only electron-neutral but also electron-poor phenols. This method operates via a silanol-directed acetoxylation, followed by a subsequent acid-catalyzed cyclization reaction into a cyclic silicon-protected catechol. A routine desilylation of the silacyle with TBAF uncovers the catechol product.