131606-91-2Relevant academic research and scientific papers
Total Synthesis of Symbioramide, a Novel Ca(2+)-ATPase Activator from Symbiodinium sp.
Yoshida, Jun,Nakagawa, Masako,Seki, Hiroko,Hino, Tohru
, p. 343 - 350 (2007/10/02)
The first total synthesis of symbioramide 1 has been accomplished by the coupling of D-erythro-dihydrosphingosine with an unusual, chiral α-hydroxy-β,γ-unsaturated fatty acid prepared from L-ascorbic acid, and simultaneously established the complete stereostructure of 1 to be (2S,2'R,3R,3'E)-N-(2'-hydroxyoctadec-3'-enoyl)dihydrosphingosine.
First Total Synthesis of Symbioramide, a Novel Ca2+-ATPase Activator from Symbiodinium sp.
Nakagawa, Masako,Yoshida, Jun,Hino, Tohru
, p. 1407 - 1410 (2007/10/02)
The first total synthesis of symbioramide (1) is described and simultaneously established the complete stereostructure of 1 to be (2S,3R,2'R,3'E)-N-(2'-hydroxy-3'-octadecenoyl)-dihydrosphingosine.
