131618-88-7

Basic information

• Product Name: bis(5,10,15,20-tetraphenylporphyrinato)hafnium(IV)
• CAS NO: 131618-88-7
• Molecular Weight: 1403.96
• Mol File: 131618-88-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(5,10,15,20-tetraphenylporphyrinato)hafnium(IV)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(5,10,15,20-tetraphenylporphyrinato)hafnium(IV)(131618-88-7)
• EPA Substance Registry System: bis(5,10,15,20-tetraphenylporphyrinato)hafnium(IV)(131618-88-7)

Safety Data

• Hazardous Substances Data: 131618-88-7(Hazardous Substances Data)

Upstream product

• 12116-66-4 bis(cyclopentadienyl)hafnium dichloride 
• 917-23-7 5,10,15,20-tetraphenyl-21H,23H-porphine 

Downstream Products

• 131635-39-7 bis(5,10,15,20-tetraphenylporphyrinato)hafnium(IV)⁽¹⁺⁾ 

Relevant articles and documents

Zirconium(IV) and Hafnium(IV) Bisporphyrinate Double Deckers: Synthesis, Spectra, Redox Potentials, and Structure

The synthesis of new zirconium and hafnium bisporphyrinate double deckers M(P)2 (M = Zr, Hf; P = OEP, TPP) is described.The complexes are characterized by UV/Vis/NIR and 1H-NMR spectroscopy and cyclic voltammetry.As compared with M = Ce, the redox potentials or the energies of the near-infrared absorption bands of the corresponding radical cations + are lower by ca. 0.2 V or higher by ca. 2000 cm-1, respectively.Hence, there is a stronger ?-? interaction between the porphyrin ligands as compared with the cerium analogues due to the smaller ionic radii of Zr(IV) and Hf(IV).X-ray crystallography of Zr(TPP)2 confirms the san dwich-like structure of the compound and the close proximity of the porphyrin ligands.