917-23-7

Usage

InChI:InChI=1/C44H30N4/c1-5-13-29(14-6-1)38-27-37-26-35-22-21-33(45-35)25-34-23-24-36(46-34)28-39-40(30-15-7-2-8-16-30)41(31-17-9-3-10-18-31)44(48-39)42(43(38)47-37)32-19-11-4-12-20-32/h1-28,45,48H/b33-25-,34-25-,35-26-,36-28-,37-26-,39-28-,43-42-,44-42-

Synthetic route

(9Z,15Z,19Z)-5,10,15,20-Tetraphenyl-5-(1H-pyrrol-2-yl)-5,21,23,24-tetrahydro-porphine → 5,15,10,20-tetraphenylporphyrin (917-23-7)

Conditions	Yield
With trifluoroacetic acid In chloroform at 20℃;	100%

Upstream product

• 109-97-7 pyrrole 
• 100-52-7 benzaldehyde 
• 872-85-5 pyridine-4-carbaldehyde 
• 4397-53-9 p-benzyloxybenzaldehyde 
• 99-61-6 3-nitro-benzaldehyde 
• 122-85-0 para-acetamidobenzaldehyde 
• 3011-34-5 4-hydroxy-3-nitrobenzaldehyde 
• 130413-37-5 4-(2-(2-chloroethoxy)ethoxy)benzaldehyde 
• 127572-74-1 4(e)-(2,5-Dihydroxyphenyl)cyclohexan-(e)-carbaldehyd 
• 82873-87-8 3-(propionyloxymethyl)benzaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 
• 93-02-7 2,5-dimethoxybenzaldehyde 
• 126442-94-2 1-Ethyl-2-{(1E,3E,5E)-7-[1-ethyl-3,3-dimethyl-1,3-dihydro-indol-(2Z)-ylidene]-hepta-1,3,5-trienyl}-5-(4-formyl-phenylcarbamoyl)-3,3-dimethyl-3H-indolium; iodide 
• 100-10-7 4-dimethylamino-benzaldehyde 

Downstream Products

• 2669-65-0 meso-tetraphenylchlorin 
• 80612-44-8 C₄₆H₃₂N₄O 
• 80612-45-9 N,N'-ethoxymethylene-meso-tetraphenylporphyrin 
• 80612-47-1 C₄₈H₃₆N₄O₂ 
• 63160-31-6 β-nitro-5,10,15,20-tetraphenylporphyrin 
• 105342-50-5 β-pyridinium-meso-tetraphenylporphyrin chloride 
• 80612-46-0 C₄₈H₃₆N₄O 
• 80641-51-6 (5Z,10Z,14Z,19Z)-21-(4-Nitro-benzyl)-5,10,15,20-tetraphenyl-porphyrin 
• 51552-53-5 N-methyl-5,10,15,20-tetraphenylporphyrin 
• 112722-96-0 N_a,N_b-dimethyl-tetraphenylporphyrin 
• 112722-98-2 Trifluoro-methanesulfonate(4Z,10Z,15Z,19Z)-21,22,24-trimethyl-5,10,15,20-tetraphenyl-22,24-dihydro-porphin-21-ium; 
• 80612-48-2 C₅₂H₃₆N₄O 
• 51552-53-5 N-methyl-5,10,15,20-tetraphenylporphyrin 
• 22843-73-8 5,10,15,20-tetrakis(4-nitrophenyl)porphyrin 

Relevant academic research and scientific papers

Physicochemical Basis for the Creation of Liquid-Phase Sensor Materials Based on Tetraaryldithiaporphyrins

Abstract: Basic properties of 5,10,15,20-tetraaryl-21-thia- and 5,10,15,20-tetraaryl-21,23-dithiaporphyrins in acetonitrile were examined spectrophotometrically. The geometry of the heteroporphyrins was optimized in the DFT approximation (hybrid functiona

Method for synthesizing tetraphenylporphyrin by using return pipe type reactor

The invention discloses a method for synthesizing tetraphenylporphyrin by using a return pipe type reactor, wherein the method comprises the steps: carrying out condensation reaction on benzaldehyde and pyrrole in an equal molar ratio in the presence of a

Tetraphenylporphyrin covalent functionalized titanium disulfide nonlinear nanometer hybrid material and preparation thereof

The invention relates to a tetraphenylporphyrin covalent functionalized titanium disulfide nonlinear nanometer hybrid material and a preparation method thereof, wherein the hybrid material is prepared from tetraphenylporphyrin diazonium salt TPP-N. 2

The construction of C(sp3)–O bond via copper porphyrin catalyzed cross-dehydrogenative coupling reaction: Substituent and electronic effect of the catalysts

The push-pull electronic and steric effect of copper porphyrin catalysts on the cross-dehydrogenative coupling (CDC) reaction between the hydroxyl group of phenol substrates and C(sp3)-H bond have been investigated. Results showed that copper porphyrin bearing electron-withdrawing, bulky steric hindrance or heteroatom of pyridyl groups could increase the catalytic activity in the reaction. 5,10,15,20-(tetrakis(4-pyridyl)porphyrin)copper (CuTPyP) was found the best among all tested catalysts. Phenol substrates bearing various functional groups afforded moderate to excellent yields (99%). Significantly, as compared to other tested copper porphyrins, CuTPyP not only exhibited remarkable higher activity but also could shorten the reaction time from 12 to 6 h.

Multifunctional Porphyrin-based dyes for cations detection in solution and thermoresponsive low-cost materials

Two β-pyrrolic substituted porphyrinic dyes 3 and 4, have been synthesized and fully characterized. Both compounds showed spectral alterations upon metal interaction indicating the complexation of the inner nitrogens in the porphyrin moiety by the metal i

Poly(L-Glutamic Acid)-Drug Conjugates for Chemo- and Photodynamic Combination Therapy

Despite the polymeric vascular disrupting agent (poly(L-glutamic acid)-graft-methoxy poly(ethylene glycol)/combretastatin A4) nanoparticles can efficiently inhibit cancer growth, their further application is still a challenge owing to the tumor

Quick and Easy Method to Dramatically Improve the Electrochemical CO2 Reduction Activity of an Iron Porphyrin Complex

The development of artificial molecular catalysts for CO2 reduction is the key to solving energy and environmental problems. Although chemical modifications can generally improve the catalytic activity of this class of compounds, they often req

Porphyrin bearing phenothiazine pincers as hosts for fullerene bindingviaconcave-convex complementarity: synthesis and complexation study

In this work, we synthesized free base porphyrin hosts,m-(PTZ)4-H2Pandp-(PTZ)4-H2P, that are functionalized with four phenothiazine moieties at themeso-positionviaa flexible ethoxy phenyl linker. The rigid and n

A series of asymmetric and symmetric porphyrin derivatives: one-pot synthesis, nonlinear optical and optical limiting properties

In this work, a series of asymmetric and symmetric porphyrin derivatives (structure types: A4, A3B1,trans-A2B2,cis-A2B2, A1B3, and B4) have been synthesizedviaa one-pot method and characterized by TLC, HPLC, FT-IR,1H-NMR and UV-Vis to identify their structures and properties. The porphyrin derivatives withtrans-A2B2andcis-A2B2structures are visually distinguishedviasingle-crystal X-ray diffraction; the crystal morphology oftrans-A2B2is a needle-like structure. All porphyrin derivatives (I-VI) have excellent nonlinear optical (NLO) and optical limiting (OL) properties, and are investigated using the standardZ-scan technique. Porphyrin derivativeIIIexhibits the maximum nonlinear absorption, nonlinear refraction coefficients and optical limitation threshold, and the values are 3.7 × 10?9m W?1, ?17 × 10?17m2W?1and 0.11 J cm?2, respectively. The results demonstrate that the introduction of different substituent numbers (mono-, di- and tri-, tetra-) and substituent sites (trans-A2B2andcis-A2B2) in the porphyrins could influence the NLO and OL properties. Structure regulation of porphyrin can lead to the adjustment of NLO and OL properties, and affect its practical NLO application in the future.

Combining metalloporphyrins and cyclometalated complexes – A luminous pair?

Cyclometalation is investigated as a method to modulate the photophysical properties of phosphorescent (benzo)porphyrins. For cyclometalation with Pt(II), 2-pyridyl groups were incorporated into three Pd(II) porphyrin complexes. Integration of the freely rotating cyclometalated 2-phenylpyridyl based motif in meso-position does not lead to notable spectral changes and only affects the luminescence decay time (about 2-fold decrease) in solution at room temperature. The decay times, however, are not affected in frozen glass at 77 K or immobilized into a rigid polystyrene matrix. In contrast, cyclometalation involving a 2-pyridyl unit in meso-position and the β-H of the porphyrin results in a large bathochromic shift (～ 1900 cm?1) of Q-bands in the absorption spectrum and the phosphorescence peak. A drastic decrease of the phosphorescence lifetime (about 20-fold) also is observed. Cyclometalation is accompanied by an increase of the singlet oxygen quantum yield to 85 % making the new dye a powerful red-light excitable 1O2 photosensitizer.