131690-91-0Relevant academic research and scientific papers
Extracyclic Stereocontrol in Addition Reaction of Crotylsilanes with 2-Substituted 2-Cyclopentenones. Stereodivergent Synthesis of (+)-Neonepetalacton and (+)-Isoneonepetalactone
Pan, Li-Rui,Tokoroyama, Takashi
, p. 1999 - 2002 (2007/10/02)
The addition reaction of E- and Z-crotylsilanes with 2-substituted 2-cyclopentenones showed the preference of erythro and threo products respectively.The refinement of the selectivity was investigated and the result was utilized for efficient syntheses of
