131711-06-3

Basic information

• Product Name: benzyl 3-(tert-butyldimethylsiloxy)-2-hydroxypropanoate
• Synonyms: benzyl 3-(tert-butyldimethylsiloxy)-2-hydroxypropanoate
• CAS NO: 131711-06-3
• Molecular Weight: 310.466
• Mol File: 131711-06-3.mol

Chemical Properties

• CAS DataBase Reference: benzyl 3-(tert-butyldimethylsiloxy)-2-hydroxypropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 3-(tert-butyldimethylsiloxy)-2-hydroxypropanoate(131711-06-3)
• EPA Substance Registry System: benzyl 3-(tert-butyldimethylsiloxy)-2-hydroxypropanoate(131711-06-3)

Safety Data

• Hazardous Substances Data: 131711-06-3(Hazardous Substances Data)

Upstream product

• 73573-57-6 rac-benzyl 2,3-dihydroxypropanoate 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 2495-35-4 benzylacrylate 

Downstream Products

• 117900-83-1 3-(tert-Butyl-dimethyl-silanyloxy)-2-(4-oxo-azetidin-2-yloxy)-propionic acid benzyl ester 
• 1131569-90-8 benzyl 2-oxo-3-(1,1,2,2-tetramethyl-1-silapropoxy)propanoate 
• 1208982-44-8 benzyl (R)-3-(tert-butyldimethylsiloxy)-2-(diphenylacetyloxy)propanoate 
• 310404-56-9 benzyl (S)-3-(tert-butyldimethylsilyloxy)-2-hydroxypropanoate 
• 131711-09-6 2-(4-Oxo-azetidin-2-yloxy)-3-(toluene-4-sulfonyloxy)-propionic acid benzyl ester 
• 131711-10-9 3-Bromo-2-(4-oxo-azetidin-2-yloxy)-propionic acid benzyl ester 
• 131711-08-5 3-Hydroxy-2-(4-oxo-azetidin-2-yloxy)-propionic acid benzyl ester 
• 117900-85-3 7-Oxo-4-oxa-1-aza-bicyclo[3.2.0]heptane-3-carboxylic acid benzyl ester 

Relevant articles and documents

Intermolecular Carboamination of Unactivated Alkenes

Herein, we report the first example of group transfer radical addition of O-vinylhydroxylamine derivatives onto unactivated alkenes. By utilizing O-vinylhydroxylamine derivatives as both the N- and C-donors, this reaction enables intermolecular carboamination of unactivated alkenes in an atom economical fashion. As the process is initiated through N-radical addition followed by C-transfer, linear carboamination products are afforded. This differs from canonical radical carbofunctionalization of olefins, which typically favors branched product owing to initiation by C-radical addition.

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