131757-87-4

Basic information

• Product Name: 5-(benzyloxymethyl)-thiophene-2-carboxaldehyde
• Synonyms: 5-(benzyloxymethyl)-thiophene-2-carboxaldehyde
• CAS NO: 131757-87-4
• Molecular Weight: 232.303
• Mol File: 131757-87-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-(benzyloxymethyl)-thiophene-2-carboxaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(benzyloxymethyl)-thiophene-2-carboxaldehyde(131757-87-4)
• EPA Substance Registry System: 5-(benzyloxymethyl)-thiophene-2-carboxaldehyde(131757-87-4)

Safety Data

• Hazardous Substances Data: 131757-87-4(Hazardous Substances Data)

Upstream product

• 4701-17-1 5-bromo-2-thiophencarboxaldehyde 
• 4118-60-9 5,6-anhydro-1,2-O-isopropylidene-β-L-idofuranose 
• 100-44-7 benzyl chloride 
• 102029-58-3 3-O-acetyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methylsulphonyl-α-D-glucofuranose 
• 16713-80-7 3-O-acetyl-1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose 
• 28585-88-8 methyl 5-deoxy-5-thio-α-D-glucopiranoside 
• 10227-17-5 3,6-di-O-acetyl-5-S-acetyl-6-O-acetyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 10227-18-6 1,2,3,4,6-penta-O-acetyl-5-thio-α-D-glucopyranoside 
• 131757-84-1 methyl 2,3,4,6-tetra-O-benzyl-5-deoxy-5-thio-α-D-glucopyranoside 

Relevant articles and documents

Photoredox Cross-Coupling: Ir/Ni Dual Catalysis for the Synthesis of Benzylic Ethers

Single-electron transmetalation has emerged as an enabling paradigm for the cross-coupling of Csp3 hybridized organotrifluoroborates. Cross-coupling of α-alkoxymethyltrifluoroborates with aryl and heteroaryl bromides has been demonstrated by employing dual catalysis with a combination of an iridium photoredox catalyst and a Ni cross-coupling catalyst. The resulting method enables the alkoxymethylation of diverse (hetero)arenes under mild, room-temperature conditions. (Chemical Equation Presented).

Synthesis of Per-O-alkylated 5-Thio-D-glucono-1,5-lactones and Transannular Participation of the Ring Sulphur Atom of 5-Thio-D-glucose Derivatives on Solvolysis under Acidic Conditions

Per-O-alkylated 5-thio-D-glucono-1,5-lactones (33)-(35) were synthesized via acetolysis or hydrolysis of the corresponding methyl glycosides (21)-(23).Transannular participation of the sulphur atom on acid methanolysis of 3,6-di-O-acetyl-5-S-acetyl-1,2-O-