4118-60-9

Upstream product

• 29747-85-1 1,2-O-isopropylidene-3,5-di-O-p-tolylsulfonyl-6-O-benzoyl-α-D-glucofuranose 
• 67-56-1 methanol 
• 37776-17-3 5,6-anhydro-3-O-benzyl-1,2-O-isopropylidene-β-L-idofuranose 
• 121613-69-2 O¹,O²-isopropylidene-O⁶-(toluene-4-sulfonyl)-α-L-glucofuranose 
• 4056-11-5 1,2-O-isopropylidene-5-O-toluenesulfonyl-α-D-glucofuranose 
• 55263-78-0 1,2-O-isopropylidene-5-O-tosyl-α-D-glucuronolactone 
• 20513-98-8 1,2-O-isopropylidene-α-D-glucofuranurono-6,3-lactone 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 118176-19-5 3-O-acetyl-1,2-O-isoprpylidene-5,6-di-O-methanesulphonyl-α-D-glucofuranose 
• 16713-80-7 3-O-acetyl-1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose 
• 102029-58-3 3-O-acetyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methylsulphonyl-α-D-glucofuranose 
• 118176-21-9 3,6-di-O-acetyl-1,2-O-isopropylidene-5-O-mesyl-α-D-glucofuranose 
• 16749-44-3 O⁶-benzoyl-O¹,O²-isopropylidene-O⁵-(toluene-4-sulfonyl)-α-D-glucofuranose 
• 24807-96-3 3-O-acetyl-1,2-O-isopropylidene-α-D-glucofuranose 

Downstream Products

• 149302-62-5 1,2-O-isopropylidene-3-O-methyl-6-O-benzyl-β-L-idofuranose 
• 149302-63-6 1,2-O-isopropylidene-3-O-methyl-5-deoxy-5-azido-6-O-benzyl-α-D-glucofuranose 
• 16505-91-2 (3R,4S,5S,6R)-6-(hydroxymethyl)tetrahydro-2H-thiopyran-2,3,4,5-tetraol 
• 10470-80-1 1,2,3,4,6-penta-O-acetyl-5-thio-α,β-D-glucopyranose 
• 131757-93-2 1-O-acetyl-2,3,4,6-tetra-O-benzyl-5-thio-α-D-glucopyranose 
• 131757-84-1 methyl 2,3,4,6-tetra-O-benzyl-5-deoxy-5-thio-α-D-glucopyranoside 
• 131757-92-1 (3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]tetrahydro-2H-thiopyran-2-one 
• 131757-87-4 5-(benzyloxymethyl)-thiophene-2-carboxaldehyde 
• 120202-61-1 6-azido-6-deoxy-L-idose 
• 5934-56-5 glucose 
• 18439-33-3 2,5-anhydro-D-glucose 
• 29747-91-9 1,2-O-isopropylidene-β-L-idofuranose 
• 16749-46-5 6-deoxy-1,2-O-isopropylidene-β-L-idofuranose 
• 60619-47-8 1,6-anhydro-β-L-idopyranose 

Relevant academic research and scientific papers

Intramolecular Displacement Reactions Involving Sulfur Leading to the Formation of 3,6-Thiaanhydro Sugar Derivatives during the Synthesis of 3,5-Dithio-glucofuranose

During a synthesis of 3,5-dithio-glucofuranose, we discovered two interesting intramolecular displacement reactions involving thiolate sulfur on the one hand and a thiirane sulfur on the other. Both generated 3,6-thiaanhydro structures. We solved the intramolecular displacement problem by using a 5-S,6-O-isopropylidene protecting group and accomplished 3,5-dithio-glucofuranose synthesis in 9 % overall yield.

Thioglucose compound and preparation method thereof

The invention provides a thioglucose compound which has the following general formula: Wherein R is selected from H or acetyl. The preparation method of the thioglucose compound is easy to obtain, low in production cost and suitable for industrial product

Chemical modification of azasugars, inhibitors of N-glycoprotein-processing glycosidases and of HIV-I infection. Review and structure-activity relationships

The synthesis of a series of analogues of the α-glucosidase inhibitor 1-deoxynojirimycin (dNM, 1) and of the α-mannosidase inhibitor 1-deoxymannojirimycin (dMM, 3) is described.The ability of dNM, dMM and a series of N-alkylated dNM and dMM derivatives to

Synthesis of Per-O-alkylated 5-Thio-D-glucono-1,5-lactones and Transannular Participation of the Ring Sulphur Atom of 5-Thio-D-glucose Derivatives on Solvolysis under Acidic Conditions

Per-O-alkylated 5-thio-D-glucono-1,5-lactones (33)-(35) were synthesized via acetolysis or hydrolysis of the corresponding methyl glycosides (21)-(23).Transannular participation of the sulphur atom on acid methanolysis of 3,6-di-O-acetyl-5-S-acetyl-1,2-O-

Improved Synthesis of 6-Deoxy-1,2-O-isopropylidene-β-L-talofuranose and 6-Deoxy-1,2-O-isopropylidene-β-L-idofuranose

The key step in the preparation of 6-deoxy-1,2-O-isopropylidene-β-L-talofuranose (7) and 6-deoxy-1,2-O-isopropylidene-β-L-idofuranose (13) is the selective exchange of the 6-O-mesyl rest of 3-O-acetyl-5,6-O-dimesyl-1,2-O-isopropylidene-α-D-allofuranose (4) and 3-O-acetyl-5,6-O-dimesyl-1,2-O-isopropylidene-α-D-glucofuranose (10) by acetate group (potassium actate/18-crown-6).