131799-53-6

Basic information

• Product Name: N-(2-Chloro-1-phenyl-1-ethylidene)isopropylamine
• Synonyms: N-(2-Chloro-1-phenyl-1-ethylidene)isopropylamine
• CAS NO: 131799-53-6
• Molecular Weight: 195.692
• Mol File: 131799-53-6.mol

Chemical Properties

• CAS DataBase Reference: N-(2-Chloro-1-phenyl-1-ethylidene)isopropylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-Chloro-1-phenyl-1-ethylidene)isopropylamine(131799-53-6)
• EPA Substance Registry System: N-(2-Chloro-1-phenyl-1-ethylidene)isopropylamine(131799-53-6)

Safety Data

• Hazardous Substances Data: 131799-53-6(Hazardous Substances Data)

Upstream product

• 532-27-4 1-chloroacetophenone 
• 75-31-0 isopropylamine 

Downstream Products

• 141814-51-9 Isopropyl-((Z)-2-methoxy-1-phenyl-vinyl)-amine 
• 56079-45-9 5,5-dimethyl-1-phenylhexane-1,4-dione 
• 4079-52-1 methoxymethyl phenyl ketone 
• 583-05-1 1-phenylpentane-1,4-dione 
• 2010-06-2 2-Amino-4-phenylthiazole 
• 1826-16-0 2-methyl-4-phenylthiazole 
• 4164-23-2 1-isopropyl-2-phenyl-aziridine 
• 111205-83-5 N,N-Diisopropyl-2-phenyl-1,2-ethanediimine 
• 77643-58-4 3-(N-Isopropyl)amino-3-phenylpropanenitrile 

Relevant articles and documents

NMR Studies of Five-Coordinate Tin Enolate: An Efficient Reagent for Halo Selective Reaction toward α-Halo Ketone or α-Halo Imine

NMR studies of tin enolates 1, in the presence of HMPA, revealed the presence of a five-coordinate O-stannyl enolate 1(h) which contributes to upfield shifts of Sn peaks in the 119Sn NMR spectrum and increased coupling constants J(119Sn-13C), compared wit

Synthesis and reactivity of α-halomethyl ketimines

The synthesis of N-(1-halo-2-alkylidene)amines, i.e. α-halomethyl ketimines, is described for the first time, utilizing the TiCl4-induced condensation of α-halomethyl ketones with primary amines. The reactivity of these new α-halomethylketimines was studied with respect to nucleophiles such as iodide, cyanide, alcohols, alkoxides, amines and thiolates. α-Halomethyl ketimines are powerful ambident electrophiles which underwent a variety of reactions leading to functionalized imines and heterocycles.