13183-28-3

Upstream product

• 2386-64-3 ethylmagnesium chloride 
• 222016-65-1 1-Chloro-1-iodo-2-phenylethane 
• 221001-53-2 1-bromo-1-iodo-2-phenylethane 
• 143097-80-7 2-bromo-4-phenylbutane 
• 1949-41-3 2-methyl-4-phenylbutanoic acid 

Relevant academic research and scientific papers

Method for preparing deuterated compound through decarboxylation and deuteration of carboxylic acid

The invention relates to a method for preparing a deuterated compound through decarboxylation and deuteration of carboxylic acid. According to the method, a carboxylic acid compound is used as a raw material, hydrogen atoms of carboxylate radicals are exc

Homocoupling of iodoarenes and bromoalkanes using photoredox gold catalysis: A light enabled Au(III) reductive elimination

The formation of homocoupled alkane byproducts have been identified in the reduction of bromoalkanes via photoredox gold catalysis with dimeric Au(I) complexes. This prompted further investigation into the mechanism of formation of these byproducts and the diversity of C-X bonds amenable to this transformation. Examples were found when considering bromoalkanes while a wide variety of iodoarenes underwent this process in good to excellent yields. The light enabled homocoupling of iodoarenes made possible by photoredox gold catalysis is reported.

Formation of rearranged Grignard reagents by carbenoid-C-H insertion

Grignard chemistry? - That is all known for more than 100 years! Thus, it is truely unexpected when a new Grignard reaction comes to light: a carbenoid C-H insertion into the α-C-H blond of a Grignard reagents.