131849-07-5Relevant articles and documents
Generation and intramolecular reactivity of acyl radicals from alkynylthiol esters under reducing tin-free conditions
Benati, Luisa,Calestani, Gianluca,Leardini, Rino,Minozzi, Matteo,Nanni, Daniele,Spagnolo, Piero,Strazzari, Samantha
, p. 1313 - 1316 (2007/10/03)
(Matrix presented) The radical chain reaction of benzenethiol with alkynylthiol esters provides a new, valuable protocol for the tin-free generation of acyl radicals that arise from intramolecular substitution at sulfur by the initial sulfanylvinyl radicals.