131926-01-7Relevant articles and documents
Preparation of Some Novel Prostanoids Based on a Tetrahydropyran Ring System
Kelly, Michael J.,Roberts, Stanley M.
, p. 787 - 797 (2007/10/02)
The prostanoids 31, 33 and 42 have been prepared from tri-O-acetyl-D-glucal 5.The key step in the formation of the prostaglandin analogues 31 and 33 involves the photocatalysed reaction between the thiocarbonate 4 and the allylstannane 21 leading to the s
Synthesis of 9-Deoxy-8,9-oxaprostaglandins
Kelly, Michael J.,Newton, Roger F.,Roberts, Stanley M.,Whitehead, John F.
, p. 2352 - 2353 (2007/10/02)
The prostanoids (14) and (18) were synthesised from the glucose derivative (1) in ca. 20 steps including, as a key reaction, the replacement of a thiocarbonate group with an allyl unit using a radical reaction.