135214-84-5

Upstream product

• 13035-13-7 4,6-O-benzylidene-1,2-dideoxy-D-glucose 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 135214-83-4 1,5-Anhydro-2-deoxy-4,6-O-(phenylmethylene)-D-arabino-hexopyranoside 
• 20072-97-3 (2S,3S,4R)-Tetrahydro-pyran-2,3,4-triol 
• 69534-73-2 3,4,6-O-tri-O-acetyl-D-glucal 
• 103302-35-8 Acetic acid (2R,3S,4R)-2,4-diacetoxy-tetrahydro-pyran-3-yl ester 

Downstream Products

• 135123-07-8 (-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate 
• 131926-03-9 (-)-O-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)tetrahydropyran-2-yl O-Phenyl Thiocarbonate 
• 131926-01-7 (-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate 
• 634606-95-4 Toluene-4-sulfonic acid (2R,3R,4R)-4-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-tetrahydro-pyran-2-ylmethyl ester 
• 135123-09-0 (+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)tetrahydropyran-2-yl>acetonitrile 

Relevant academic research and scientific papers

Highly Stereoselective [3+2] Cycloadditions of Nitrile Oxides to Methyl 4-O-Acryloyl-6-deoxy-2,3-O-(t-butyldimethylsilyl)-α-D-glucopyranoside

The [3+2] cycloadditions of benzonitrile oxide or pivalonitrile oxide to methyl 4-O-acryloyl-6-deoxy-2,3-di-O-(t-butyldimethylsilyl)-α -D-glucopyranoside provided the respective adducts, each as virtually a single diastereomer. By reductive removal of the

Preparation of Some Novel Prostanoids Based on a Tetrahydropyran Ring System

The prostanoids 31, 33 and 42 have been prepared from tri-O-acetyl-D-glucal 5.The key step in the formation of the prostaglandin analogues 31 and 33 involves the photocatalysed reaction between the thiocarbonate 4 and the allylstannane 21 leading to the s

Synthesis of 9-Deoxy-8,9-oxaprostaglandins

The prostanoids (14) and (18) were synthesised from the glucose derivative (1) in ca. 20 steps including, as a key reaction, the replacement of a thiocarbonate group with an allyl unit using a radical reaction.