13195-85-2Relevant academic research and scientific papers
The Bromination of Cyclohexanone-2-carboxamide.
Bischoff, Christian,Schroeder, Edith
, p. 616 - 620 (2007/10/02)
Cyclohexanone-2-carboxamide with bromine forms 6-bromo-cyclohexanone-2-carboxamide (2) or 2-bromo-cyclohexanone-2-carboxamide (3).Via Faworski-rearrangement the reaction of 2 and ammonia or aamines gives trans-cyclopentanedicarboxamides (5a-f). 3 and thiourea form the aminothiazole derivative 6.Pyridinium salt 7 is formed by reaction of 2 and pyridine. 7 and phenylhydrazine form the phenyl-indazolonoyl-hydrazine 8. 1 and sodium hypochlorite yield 2-hydroxy-cyclohexanone-2-carboxamide (9).
