131971-71-6Relevant academic research and scientific papers
RHODIUM(I)-CATALYSED REACTIONS OF ENAMIDES WITH 1,3-DIENES: DIFFERENT SYNTHETIC PATHWAYS DEPENDING ON SUBSTITUTION AT NITROGEN
Costa, Mirco,Chiusoli, Gian Paolo,Salvadori, Flavio,Bocelli, Gabriele
, p. 589 - 594 (2007/10/03)
New reactions of n-vinylamides (enamides) with 1,3-dienes are described.Under the catalytic action of rhodium(I) complexes and at mild temperature N,O-acetals are formed with secondary amides.Tertiary amides give N-dienylamides.The origin of this behaviou
Control of Regioselectivity by Chelating Substrates in Some Rhodium(I) and Rhodium(III)-catalysed Reactions of Butadiene
Bocelli, Gabriele,Chiusoli, Gian Paolo,Costa, Mirco,Michelotti, Michela
, p. 1347 - 1358 (2007/10/02)
Rhodium(I) catalyses the addition of butadiene to chelating substrates such as N-allylamides of organic acids, or alkylamides of but-3-enoic or pent-4-enoic acids, under mild conditions, to give linear products exclusively.No reaction occurs in the absenc
Rhodium-catalysed Diene-Allylamine Coupling Reaction and Palladium Catalysis of Formation of the Active Rhodium Species
Chiusoli, Gian Paolo,Costa, Mirco,Fiore, Antonio
, p. 1303 - 1304 (2007/10/02)
Diene-allylamide carbon-carbon coupling reaction occurs regioselectively under the catalytic action of rhodium complex, whose formation is catalysed by palladium(0)
