1319726-07-2Relevant academic research and scientific papers
A [Pd]-mediated ω-alkynone cycloisomerization approach for the central tetrahydropyran unit and the synthesis of C(31)-C(48) fragment of aflastatin A
Narute, Sachin B.,Kiran, Neella Chandra,Ramana, Chepuri V.
, p. 5469 - 5475 (2011/09/12)
A concise assembly of the central tetrahydropyran unit of aflastatin A featuring a Pd-mediated alkynone cycloisomerization to provide a glycal and its subsequent stereoselective hydroboration to deliver the requisite stereochemistry at C(33) and C(34) cen
