1319735-37-9

Basic information

• Product Name: C₅H₆N₂*C₆H₃Cl₂NO₃
• CAS NO: 1319735-37-9
• Molecular Weight: 302.117
• Mol File: 1319735-37-9.mol

Chemical Properties

• CAS DataBase Reference: C₅H₆N₂*C₆H₃Cl₂NO₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₅H₆N₂*C₆H₃Cl₂NO₃(1319735-37-9)
• EPA Substance Registry System: C₅H₆N₂*C₆H₃Cl₂NO₃(1319735-37-9)

Safety Data

• Hazardous Substances Data: 1319735-37-9(Hazardous Substances Data)

Upstream product

• 504-29-0 2-aminopyridine 
• 618-80-4 2,6-dichloro-4-nitrophenol 

Relevant articles and documents

Spectroscopic investigation on proton transfer reaction in the complex of 2-aminopyridine with 2, 6-dichloro-4-nitrophenol in different solvents

Proton transfer (PT) reaction between 2-aminopyridine (2AP) with 2,6-dichloro-4-nitrophenol (DCNP) has been investigated spectrophotometrically in methanol (MeOH), acetonitrile (AN) and acetonitrile with 1,2-dichloroethane binary mixtures (1:1, ANDEI) and (3:1, ANDEII). A long wavelength band in the range 395-424 nm due to the proton transfer complex formation has been recorded. The formation constants of the PT-reaction (KPT) have been estimated using Benesi-Hildebrand equation. It has been found that KPT recorded larger value in AN than MeOH and binary mixtures. This result was interpreted in terms of solvatochromic parameters like, solvent polarizability (π*), hydrogen bond donor (α), and hydrogen bond acceptor (β). The molecular composition of the PT-complex has been identified by Job's and photometric titration methods where 1:1 complex is formed. Based on the rapidity and simplicity of the PT-reaction as well as the stability and simple composition of the formed complex, a rapid, accurate and sensitive spectrophotometric method for determination of 2AP was proposed. In addition, the solid PT-complex (2AP-DCNP) has been isolated and characterized using elemental analyses and FTIR measurements.