1319744-18-7Relevant academic research and scientific papers
Palladium nanoparticle-catalyzed direct ethynylation of aliphatic carboxylic acid derivatives via C(sp3)-H bond functionalization
Al-Amin, Mohammad,Arisawa, Mitsuhiro,Shuto, Satoshi,Ano, Yusuke,Tobisu, Mamoru,Chatani, Naoto
, p. 1631 - 1637 (2014/06/09)
We have developed a sulfur-modified, gold-supported palladium material (SAuPd) with palladium, Pd, nanoparticles on its surface; it is a recyclable, low-leaching Pd catalyst. Here we report, using SAuPd, the first example of Pd nanoparticle-catalyzed, una
Palladium-catalyzed direct ethynylation of C(sp3)-H bonds in aliphatic carboxylic acid derivatives
Ano, Yusuke,Tobisu, Mamoru,Chatani, Naoto
, p. 12984 - 12986 (2011/10/05)
The first catalytic alkynylation of unactivated C(sp3)-H bonds has been accomplished. The method allows for the straightforward introduction of an ethynyl group into aliphatic acid derivatives under palladium catalysis. This new reaction can be
