132029-03-9Relevant academic research and scientific papers
C=N Bond Activation and Hydration by an Iron(III) Complex with Asymmetric Sulfur Oxygenation
Wu, Yun-Ru,Chang, Chia-Ming,Wang, Chia-Chi,Hsieh, Chang-Chih,Horng, Yih-Chern
, p. 840 - 843 (2017)
The presence of asymmetric cysteine sulfur-oxygenation donors, consisting of sulfenate (SO), sulfinate (SO2), and thiolate (S), around a trivalent iron is essential for the catalytic function of Fe- or Co-type nitrile hydratase (NHase). To gain
Synthesis of Nickel(II), Coper(II), Zinc(II), and Cadmium(II) Complexes of 2-pyrrole and 2-pyrrole by the Electrochemical Cleavage of a Disulphide Bond: the Crystal Structure of Bis 2-thiophenolato..
Castro, Jesus,Romero, Jaime,Garcia-Vazquez, Jose A.,Duran, Maria L.,Castineiras, Alfonso,et al.
, p. 3255 - 3258 (1990)
The electrochemical oxidation of anodic metal (nickel, copper, zinc, or cadmium) in acetonitrile solutions of the Schiff bases derived from 2-pyrrolecarbaldehyde and bis(2-aminophenyl)disulphide (H2L2) or cysteamine (H2L2') gives compounds , or .The crystal structure of bisthiophenolato>zinc(II) is orthorhombic, space group Pbca with a = 13.764(3), b = 17.819(1), c = 16.593(2) Angstroem, and Z = 8.The zinc atom has ZnS2N2 distorted tetrahedral stereochemistry and the pyrrolic nitrogen atoms are not co-ordinated.
