Synthesis of Nickel(II), Coper(II), Zinc(II), and Cadmium(II) Complexes of 2-pyrrole and 2-pyrrole by the Electrochemical Cleavage of a Disulphide Bond: the Crystal Structure of Bis 2-thiophenolato..

DOI: 10.1039/DT9900003255

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Journal of the Chemical Society, Dalton Transactions p. 3255 - 3258 (1990)

Update date:2022-08-11

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Authors:

Castro, Jesus

Romero, Jaime

Garcia-Vazquez, Jose A.

Duran, Maria L.

Castineiras, Alfonso

et al. et al.

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Article abstract of DOI:10.1039/DT9900003255

The electrochemical oxidation of anodic metal (nickel, copper, zinc, or cadmium) in acetonitrile solutions of the Schiff bases derived from 2-pyrrolecarbaldehyde and bis(2-aminophenyl)disulphide (H2L2) or cysteamine (H2L2') gives compounds , or .The crystal structure of bis<2-<(pyrrol-2-yl)methyleneamino>thiophenolato>zinc(II) is orthorhombic, space group Pbca with a = 13.764(3), b = 17.819(1), c = 16.593(2) Angstroem, and Z = 8.The zinc atom has ZnS2N2 distorted tetrahedral stereochemistry and the pyrrolic nitrogen atoms are not co-ordinated.

Full text of DOI:10.1039/DT9900003255

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