132039-45-3Relevant academic research and scientific papers
Iron-Catalyzed arylation of heterocycles via directed c-h bond activation
Sirois, John J.,Davis, Riley,Deboef, Brenton
supporting information, p. 868 - 871 (2014/03/21)
The iron-catalyzed arylation of aromatic heterocycles, such as pyridines, thiophenes, and furans, has been achieved. The use of an imine directing group allowed for the ortho functionalization of these heterocycles with complete conversion in 15 min at 0
UV promoted phenanthridine syntheses from oxime carbonate derived iminyl radicals
McBurney, Roy T.,Slawin, Alexandra M. Z.,Smart, Laura A.,Yu, Yanping,Walton, John C.
supporting information; experimental part, p. 7974 - 7976 (2011/08/08)
Oxime carbonates were found to be excellent precursors for the clean and direct generation of iminyl radicals under UV irradiation. Suitably functionalised iminyls underwent cyclisations yielding various phenanthridines and also substituted quinolines and
Regioselective Synthesis of 2-Functionalized Thiophenes by Condensation of α-Mercapto Compounds with β-Aminoenone Derivatives
Alberola, Angel,Andres, Jose M.,Gonzalez, Alfonso,Pedrosa, Rafael,Pradanos, Pedro
, p. 2537 - 2547 (2007/10/02)
2-Acylthiophenes and ethyl 2-thiophenecarboxylates are prepared regioselectively by reaction of 3-chloroenones and 2-acylenammonium chlorides with α-mercapto derivatives in good to moderate yields.
