132041-61-3Relevant academic research and scientific papers
Practical Cross-Coupling between O-Based Electrophiles and Aryl Bromides via Ni Catalysis
Cao, Zhi-Chao,Luo, Qin-Yu,Shi, Zhang-Jie
supporting information, p. 5978 - 5981 (2016/12/09)
Cross-coupling of various O-based electrophiles with aryl bromides was developed through Ni-catalyzed C-O activation in the presence of magnesium. Beside carboxylates, carbamates, and ethers, phenols exhibited excellent reactivity under modified conditions. This chemistry was featured as a simple and environmentally benign process with low catalyst loading and easy manipulations. The method exhibited broad substrate scopes.
Mutual activation: Suzuki-Miyaura coupling through direct cleavage of the sp2 C-O bond of naphtholate
Yu, Da-Gang,Shi, Zhang-Jie
supporting information; experimental part, p. 7097 - 7100 (2011/09/30)
Working together: A new approach of mutual activation between naphtholates and aryl boronic acid derivatives by the formation of borates to facilitate the Suzuki-Miyaura coupling through direct cleavage of the sp2 C-O bond by nickel catalysis is described (see scheme; R′: annulated ring system). Various naphtholates and aryl boronic acid derivatives could be directly coupled in good yields. Copyright
Methylation of arenes via Ni-catalyzed aryl C-O/F activation
Guan, Bing-Tao,Xiang, Shi-Kai,Wu, Tao,Sun, Zuo-Peng,Wang, Bi-Qin,Zhao, Ke-Qing,Shi, Zhang-Jie
, p. 1437 - 1439 (2008/12/21)
Aryl C-O and C-F can be transformed into C-Me via Ni-catalyzed coupling with MeMgBr under mild conditions. The Royal Society of Chemistry.
