132066-06-9Relevant academic research and scientific papers
Tuning macrocycles to design 'turn-on' fluorescence probes for manganese(ii) sensing in live cells
Bakthavatsalam, Subha,Sarkar, Anindita,Rakshit, Ananya,Jain, Shubhi,Kumar, Amit,Datta, Ankona
, p. 2605 - 2608 (2015)
We tune the coordination environment of macrocyclic ligands to design two novel fluorescence sensors for Mn2+. The BODIPY-based Mn2+ sensor M1 affords an excellent, 52 fold, fluorescence 'turn-on' response despite the paramagnetic nature of Mn2+. The lipophilic probe is cell-permeable and confocal imaging demonstrates that the sensor distinctly detects Mn2+ within live cells. This journal is
Aqueous ring opening of N-tosylaziridine with aniline derivatives
Zhu, Mengping,Moasser, Bahram
experimental part, p. 2288 - 2291 (2012/07/28)
A series of N-(p-X-phenyl)-N'-(p-toluenesulfonyl)1,2-ethylenediamines compounds, TsN(H)CH2CH2N(H)PhX, were synthesized by the uncatalyzed ring opening reaction of N-tosylaziridine with p-X-aniline derivatives in pure water at 50 °C. No solvolysis product was observed and the only side product was that of a subsequent ring opening reactions of N-tosylaziridine with the product anilines leading to substituted diethylenetriamines, XPhN(CH2CH2NTs)2.
POLYAZACYCLIC COMPOUNDS. PART I. SYNTHESIS OF ARYLSULFONYL DERIVATIVES OF 1,4,7,10-TETRAAZACYCLODODECANE AND 1-OXA-4,7,10-TRIAZACYCLODODECANE SUBSTITUTED AT REQUIRED NITROGEN ATOMS
Sienkiewicz, Juliusz,Goss, Ewa,Stanczak, Andrzej
, p. 77 - 86 (2007/10/02)
A method of preparation of new polyazamacrocyclic compounds substituted at required nitrogen atoms is given based on the example of synthesis of the title derivatives.The method consists in the cyclocondensation of substrates, of which at least one has a tertiary amino group present in the macrocyclic compound.
