132142-96-2

Upstream product

• 97997-91-6 (Z)-6-(trimethylsilyl)hex-4-en-1-ol 
• 132143-10-3 (2S,3'S)-1-Acetyl-2-(2-benzyloxy-ethyl)-1'-(tert-butyl-dimethyl-silanyl)-1,2-dihydro-spiro[indole-3,3'-pyrrolidine]-2',5'-dione 
• 132142-95-1 (2S,3'S)-2-(2-Benzyloxy-ethyl)-1'-(tert-butyl-dimethyl-silanyl)-1,2-dihydro-spiro[indole-3,3'-pyrrolidine]-2',5'-dione 
• 132143-09-0 (2R,3'R)-1-Acetyl-2-(2-benzyloxy-ethyl)-1,2-dihydro-spiro[indole-3,3'-pyrrolidine]-2',5'-dione 
• 132143-08-9 1-(tert-Butyl-dimethyl-silanyl)-3-(2-nitro-phenyl)-pyrrolidine-2,5-dione 
• 132142-94-0 1-(tert-butyldimethylsilyl)-3-(2'-aminophenyl)pyrrolidine-2,5-dione 
• 19790-60-4 3-Benzyloxypropanal 
• 4799-68-2 3-benzyloxypropan-1-ol 
• 58594-50-6 3-(2'-nitrophenyl)pyrrolidine-2,5-dione 
• 772-01-0 2-phenyl-1,3-dioxane 
• 132143-11-4 (2S,3'S)-1-Acetyl-2-(2-benzyloxy-ethyl)-1'-((Z)-6-trimethylsilanyl-hex-4-enyl)-1,2-dihydro-spiro[indole-3,3'-pyrrolidine]-2',5'-dione 

Downstream Products

• 132143-13-6 (2R,3'R)-1-Acetyl-2-(2-benzyloxy-ethyl)-2'-ethoxy-1'-((Z)-6-trimethylsilanyl-hex-4-enyl)-1,2-dihydro-spiro[indole-3,3'-pyrrolidin]-5'-one 
• 132143-00-1 C₂₈H₃₂N₂O₃ 
• 132143-02-3 C₂₇H₃₀N₂O₄ 
• 132143-01-2 (2R,3'R)-1-Acetyl-2-(2-benzyloxy-ethyl)-1'-hex-5-enyl-2'-hydroxy-1,2-dihydro-spiro[indole-3,3'-pyrrolidin]-5'-one 
• 132143-03-4 C₂₉H₃₆N₂O₅ 

Relevant academic research and scientific papers

Synthesis of the aspidosperma skeleton through allylsilane N-acyliminium cyclization

A highly stereoselective synthesis of the Aspidosperma ring system is described, based on a combination of two stereocontrolled processes. The first features a base-catalyzed cyclization of the imine 5 to generate the indoline 4. The second involves the f