132142-97-3

Upstream product

• 97997-91-6 (Z)-6-(trimethylsilyl)hex-4-en-1-ol 
• 3464-18-4 3-phenylpyrrolidine-2,5-dione 

Downstream Products

• 132142-99-5 5-ethenyl-7-methyl-7-phenyl-1-azabicyclo<4.3.0>nonan-9-one 
• 132142-99-5 5-ethenyl-7-methyl-7-phenyl-1-azabicyclo<4.3.0>nonan-9-one 
• 132142-99-5 5-ethenyl-7-methyl-7-phenyl-1-azabicyclo<4.3.0>nonan-9-one 
• 132142-99-5 5-ethenyl-7-methyl-7-phenyl-1-azabicyclo<4.3.0>nonan-9-one 
• 132142-71-3 1-(6-trimethylsilyl-4-hexenyl)-5-ethoxy-4-methyl-4-phenyl-2-pyrrolidinone 
• 132142-98-4 (4R,5R)-5-Hydroxy-4-methyl-4-phenyl-1-((Z)-6-trimethylsilanyl-hex-4-enyl)-pyrrolidin-2-one 
• 132142-98-4 (4R,5S)-5-Hydroxy-4-methyl-4-phenyl-1-((Z)-6-trimethylsilanyl-hex-4-enyl)-pyrrolidin-2-one 

Relevant academic research and scientific papers

Synthesis of the aspidosperma skeleton through allylsilane N-acyliminium cyclization

A highly stereoselective synthesis of the Aspidosperma ring system is described, based on a combination of two stereocontrolled processes. The first features a base-catalyzed cyclization of the imine 5 to generate the indoline 4. The second involves the f