132149-66-7

Basic information

• Product Name: dimethyl 3,3′-(6,6′-dihydroxybiphenyl-3,3′-diyl)bis[2-(benzyloxycarbonylamino)propanoate]
• Synonyms: dimethyl 3,3′-(6,6′-dihydroxybiphenyl-3,3′-diyl)bis[2-(benzyloxycarbonylamino)propanoate]
• CAS NO: 132149-66-7
• Molecular Weight: 656.689
• Mol File: 132149-66-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: dimethyl 3,3′-(6,6′-dihydroxybiphenyl-3,3′-diyl)bis[2-(benzyloxycarbonylamino)propanoate](CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 3,3′-(6,6′-dihydroxybiphenyl-3,3′-diyl)bis[2-(benzyloxycarbonylamino)propanoate](132149-66-7)
• EPA Substance Registry System: dimethyl 3,3′-(6,6′-dihydroxybiphenyl-3,3′-diyl)bis[2-(benzyloxycarbonylamino)propanoate](132149-66-7)

Safety Data

• Hazardous Substances Data: 132149-66-7(Hazardous Substances Data)

Upstream product

• 13512-31-7 N-(benzyloxycarbonyl)-L-tyrosine methyl ester 

Downstream Products

• 1394296-00-4 (2S,2′S)-dimethyl 3,3′-(5,5′-dibromo-6,6′-dihydroxybiphenyl-3,3′-diyl)bis(2-(benzyloxycarbonylamino)propanoate) 
• 79067-77-9 bastadin-3 
• 1394296-07-1 (2S,2′S)-3,3′-(4,8-dibromodibenzo[d,f][1,3]dioxepine-2,10-diyl)-bis(2-amino-N-(3-bromo-4-hydroxyphenethyl)propanamide) 
• 1394296-06-0 benzyl (2S,2′S)-3,3′-(4,8-dibromodibenzo[d,f][1,3]dioxepine-2,10-diyl)bis(1-(3-bromo-4-hydroxyphenethylamino)-1-oxopropane-3,2-diyl)dicarbamate 
• 1394296-04-8 (2S,2′S)-3,3′-(4,8-dibromodibenzo[d,f][1,3]dioxepine-2,10-diyl)-bis(2-(benzyloxycarbonylamino)propanoic acid) 

Relevant articles and documents

PROCESS FOR MAKING BIARYL-BRIDGED CYCLIC PEPTIDES

The invention provides a method of preparing a biaryl-bridged cyclic peptide compound of Formula (I), where R1, R2, R3, R4, R5, R8, R7, R8, R9, R10, R11, R12, n and m are as defined in the specification. The biaryl-bridged cyclic peptides of Formula (I) are used in the preparation of pharmaceutically active substances, such as, for example, arylomycin and arylomycin analogues.

First total synthesis of dioxepine bastadin 3

The synthesis of dioxepine bastadin 3, a tyrosine-tyramine derivative with a dibenzo-1,3-dioxepine scaffold that is rarely present among natural products, is described. The dibenzo-1,3-dioxepine ring was formed early in the sequence and the (E)-2-(hydroxy

SYNTHESIS OF ANALOGUES OF THE BIPHENOMYCIN ANTIBIOTICS

The oxidative coupling of L-tyrosine derivatives with vanadium oxyhalides has given dityrosine intermediates which were cyclized to give analogues of the biphenomycin antibiotics.