1322144-75-1Relevant articles and documents
Synthesis of multi-substituted pyridines from ylidenemalononitriles and their emission properties
de Souza, Juliana M.,Abdiaj, Irini,Chen, Jiaqi,Hanson, Kenneth,de Oliveira, Kleber T.,McQuade, D. Tyler
, p. 1991 - 1999 (2021/03/16)
Numerous methodologies to obtain pyridines from ylidenemalononitriles are described in the literature. Nevertheless, they are limited to the use of microwave or conventional heat and few lead to 2,3,4 or 2,3,4,5-substituted pyridines as multi-proposal molecular scaffolds or evenuniversal pyridines. Herein, we present a mild and facile solvent-free methodology to obtain a scope of multi-substituted pyridines at room temperature. We also report an example where one of the resulting amino-nicotinonitriles exhibits a preliminary evidence of aggregation-induced emission (AIE).
Solventless convenient synthesis of new cyano-2-aminopyridine derivatives from enaminonitriles
Villemin, Didier,Belhadj, Zahira,Cheikh, Nawel,Choukchou-Braham, Noureddine,Bar, Nathalie,Lohier, Jean-Fran?ois
, p. 1664 - 1668 (2013/03/28)
A synthesis of novel 4-substituted-3-cyano-2-aminopyridines using enaminonitriles and various primary amines was established under microwave irradiation and solvent-free conditions. Structures of the new compounds were characterized by IR, MS, 1/sup